refractive index of sapphire ≈ 1.77 so sin(i)/sin(45) = 1.77, sin(i) = 1.77*sin(45)
relative refractive index between the two materials is sin(57)/sin(45) ≈ 1.186, sin(57) = 1.186*sin(45)
refractive index of other material is sin(i)/sin(57) = 1.77*sin(45)/(1.186*sin(45)) ≈ 1.5
Likely material: Glass.