Think of a right-angled triangle. If the cosine of an angle is 2/3, the side adjacent to the angle is proportional to 2 and the hypotenuse is proportional to 3, so the opposite side is proportional to √(32 - 22) = √5.
Since tan of the angle is opposite/adjacent then tan(cos-1(2/3)) = (√5)/2
See if you can do something similar with the other one (remembering that in the fourth quadrant sin is negative but cos is positive).
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